Syllabus – CHEM 1104, General Chemistry II
Instructor:
Dr. Alexander Y. Fadeev fadeeval@shu.edu (973)-275-2807
Office: 319 McNulty Office hours: M,W 2-3PM and by appointment.
Course description and objectives: The primary objective of this course is to develop your understanding of the empirical and theoretical foundations of the chemical sciences. Topics include the foundations of thermodynamics and energetics of chemical processes; principles of chemical equilibrium; acid-base and other solution equilibria; rates of chemical reactions and reaction mechanisms; electron transfer reactions and electrochemistry; the transition metals and the main group elements; nuclear chemistry and radiochemistry, macromolecules and polymers.
Prerequisites: CHEM1103.
Required Texts: Chemistry – Third Edition, J. Olmsted III & and G.M. Williams, John Wiley, 2002, ISBN-0-471-39071-2 (with Technology Integrator CD).
Chemical Principles in the Laboratory, Seventh Edition, E.J. Slowinski, W.C. Wolsey, & W.L. Masterson, Saunders, 2001.
Semester schedule: A day by day schedule of all course activities including exams, labs, and lectures is available. Please refer to this schedule on a daily basis.
Required Tools:
Calculators: You must have a scientific calculator for this course. The calculator must be able to do the following: scientific notation (EXP or EE). logarithms (log and ln), inverse functions (INV or 10x or yx), square roots. You are responsible for having your own calculator available for use during quizzes and exams.
Bound Laboratory Notebook: You are required to have a laboratory notebook with permanently bound pages. You must bring this laboratory notebook with you to lab in order to collect lab data. You may not refer to the printed laboratory manual (Chemical Principles in the Laboratory) during lab. Prior to each laboratory you may transfer to your laboratory notebook all the notes and data tables that are necessary for you carry out that lab.
Safety Goggles and Lab Coats: You will be supplied with this required safety gear prior to the first laboratory; if these are lost or misplaced, you must purchase replacements. You cannot participate in any laboratory activity without wearing this required safety gear.
Grading:
Quizzes: There will be a number of unannounced quizzes given during lecture periods throughout the semester. The subject of each quiz will generally be a class topic discussed since the last quiz.
Mid-term Exam: There will be one mid-term exams currently scheduled for February 16 and March 22 respectively. The first exam will be based on the material covered in Chapters 12-14 of the text. The second exam will be based on the material covered in Chapters 15-18 of the text.
Laboratory & Assignments: Each laboratory will require some kind of report which will be graded. In addition, you will receive a participation grade in this category from your laboratory instructors based on your willingness to seek assistance in working problems.
Final Examination: Final (comprehensive) exam is currently scheduled on May 4, 2004. The exam will be based on the material covered in Chapters 11-21 of the text.
The final grade will reflect the following distribution of course contributions:
|
|
Points/each |
Points total |
% in the final grade |
|
Mid-term exam
|
100 |
100 |
17% |
|
Final exam |
200 |
200 |
33% |
|
Quizes |
10 |
Normalized to 100 |
17% |
|
Lab. reports |
20 |
Normalized to 200 |
33% |
|
Total (max) |
|
600 |
100% |
The final letter grades will be calculated as follows:
A≥90%; B+≥85%; B≥80%; C+≥75%; C≥70%; D≥60%; F<60%)
Course Schedule
|
Date |
Day |
Reading |
Lecture Topic |
Lab Schedule |
|
1/12 |
M |
10.6 |
Introduction. Phase equilibria. |
No lab |
|
1/13 |
T |
|
Lab safety briefing |
No lab |
|
1/14 |
W |
10.7 |
Osmosis, Cell membranes, Surfactants |
No lab |
|
1/15 |
R |
|
No classes. Martin Luther King Jr. Birthday |
No lab |
|
|
|
|
|
|
|
1/19 |
M |
12.1 |
Thermodynamic definitions |
No lab |
|
1/20 |
T |
|
Check-In & Lab safety |
No lab |
|
1/21 |
W |
12.2-12.3 |
Energy, Heat, Work. The 1-st Law |
Chek-in, BB |
|
1/22 |
R |
12.4-12.5 |
Enthalpy, Heats of reactions |
Chek-in, CC, AB |
|
|
|
|
|
|
|
1/26 |
M |
13.1-13.2 |
Spontaneity. Energy and disorder |
Chek-in, BA |
|
1/27 |
T |
|
Exp. 19 safety briefing and prep |
Chek-in, AA |
|
1/28 |
W |
13.3 |
Entropy and the 2-d Law |
Exp. 19 – Freezing point depression, BB |
|
1/29 |
R |
13.4-13.6 |
Free energy. Bioenergetics |
Exp. 19, CC, AB |
|
|
|
|
|
|
|
2/2 |
M |
Chs. 12 and 13 |
Review of Thermodynamics |
Exp. 19, BA |
|
2/3 |
T |
|
Exp. 20 safety briefing and prep |
Exp. 19, AA |
|
2/4 |
W |
14.1-14.3 |
Reaction rates and reaction mechanisms |
Exp. 20 – Rates of chem. Reactions, BB |
|
2/5 |
R |
14.1-14.3 |
Reaction rates and reaction order |
Exp. 20, CC, AB |
|
|
|
|
|
|
|
2/9 |
M |
14.4-14.6 |
Reaction rates and temperature |
Exp. 20, BA |
|
2/10 |
T |
|
Exp. 22 safety briefing and prep |
Exp. 20, AA |
|
2/11 |
W |
14.6 |
Activation energy. |
Exp. 22 – Chem. Equilibrium, BB |
|
2/12 |
R |
14.7 |
Catalysis |
Exp. 22, CC, AB |
|
|
|
|
|
|
|
2/16 |
M |
Ch. 14 |
Review of Kinetics |
Exp. 22, BA |
|
2/17 |
T |
|
Exp. 23 safety briefing and prep |
Exp. 22, AA |
|
2/18 |
W |
15.1-15.2 |
Chemical equilibrium. Equilibrium constant |
Exp. 23 – Equilibrium constant, BB |
|
2/19 |
R |
15.3-15.4 |
Thermodynamics and equilibrium |
Exp. 23, CC, AB |
|
|
|
|
|
|
|
2/23 |
M |
15.5-15.6 |
Working with equilibria I |
Exp. 23, BA |
|
2/24 |
T |
|
Exp. 24 safety briefing and prep |
Exp. 23, AA |
|
2/25 |
W |
15.5-15.6 |
Working with equilibria II |
Exp. 24 – Molar mass determination, BB |
|
2/26 |
R |
16.1-16.3 |
Acid-base equilibria I |
Exp. 24, CC, AB |
|
|
|
|
|
|
|
3/1 |
M |
16.4-16.7 |
Acid-base equilibria II |
Exp. 24, BA |
|
3/2 |
T |
17.1-17.3 |
Buffers |
Exp. 24, AA |
|
3/3 |
W |
17.4-17.5 |
Solubility equilibria. Complexes |
|
|
3/4 |
R |
Chs. 12-17 |
Mid-term Exam |
|
|
Date |
Day |
Reading |
Lecture Topic |
Lab Schedule |
|
3/8-11 |
M-R |
|
Spring Break |
|
|
|
|
|
|
|
|
3/15 |
M |
18.1-18.4 |
Redox reactions and cell potentials |
|
|
3/16 |
T |
|
Exp. 25 safety briefing and prep |
|
|
3/17 |
W |
18.5-18.6 |
The Nernst equation. |
Exp. 25 – Buffers, BB |
|
3/18 |
R |
18.7 |
Elelctrolysis |
Exp. 25, CC, AB |
|
|
|
|
|
|
|
3/22 |
M |
Chs. 15-18 |
Review of chemical equilibria |
Exp. 25, BA |
|
3/23 |
T |
|
Exp. 26 safety briefing and prep |
Exp. 25, AA |
|
3/24 |
W |
19.1-19.3 |
Transitional metals. Complexes |
Exp. 26 – Solubility, BB |
|
3/25 |
R |
19.4 |
Metallurgy |
Exp. 26, CC, AB |
|
|
|
|
|
|
|
3/29 |
M |
19.5-19.6 |
Transitional metals. Applications |
Exp. 26, BA |
|
3/30 |
T |
|
Exp. 28 safety briefing and prep |
Exp. 26, AA |
|
3/31 |
W |
20.1-20.3 |
The main group elements. Metals |
Exp. 28- Hardness of water, BB |
|
4/1 |
R |
20.4-20.5 |
The main group elements. Phosphorus |
Exp. 28, CC, AB |
|
|
|
|
|
|
|
4/5 |
M |
20.6 |
The main group elements. Sulfur, Halogens |
Exp. 28, BA |
|
4/6 |
T |
|
|
Exp. 28, AA |
|
4/7 |
W |
21.1-21.2 |
Nuclear chemistry and nuclear decay |
No lab |
|
4/8 |
R |
|
Holy Thursday |
No lab |
|
|
|
|
|
|
|
4/12 |
M |
|
Easter Monday |
No lab |
|
4/13 |
T |
|
Exp. 30 safety briefing and prep |
No lab |
|
4/14 |
W |
21.3-21.4 |
Nuclear fission and nuclear fusion |
Exp. 30 – Redox titration, BB |
|
4/15 |
R |
21.5-21.7 |
Radioactivity |
Exp. 30, CC, AB |
|
|
|
|
|
|
|
4/19 |
M |
11.1-11.4 |