Syllabus – CHEM 1104, General Chemistry II

 

 

Instructor:

Dr. Alexander Y. Fadeev          fadeeval@shu.edu                                (973)-275-2807

Office: 319 McNulty                             Office hours: M,W 2-3PM and by appointment.

 

Course description and objectives:  The primary objective of this course is to develop your understanding of the empirical and theoretical foundations of the chemical sciences.  Topics include the foundations of thermodynamics and energetics of chemical processes; principles of chemical equilibrium; acid-base and other solution equilibria; rates of chemical reactions and reaction mechanisms; electron transfer reactions and electrochemistry; the transition metals and the main group elements; nuclear chemistry and radiochemistry, macromolecules and polymers.

 

Prerequisites: CHEM1103.

 

Required Texts: Chemistry – Third Edition, J. Olmsted III & and G.M. Williams, John Wiley, 2002, ISBN-0-471-39071-2 (with Technology Integrator CD).

Chemical Principles in the Laboratory, Seventh Edition, E.J. Slowinski, W.C. Wolsey, & W.L. Masterson, Saunders, 2001.

 

Semester schedule: A day by day schedule of all course activities including exams, labs, and lectures is available. Please refer to this schedule on a daily basis.

 

Required Tools:

Calculators:  You must have a scientific calculator for this course. The calculator must be able to do the following: scientific notation (EXP or EE). logarithms (log and ln), inverse functions (INV or 10x or yx), square roots. You are responsible for having your own calculator available for use during quizzes and exams.

 

Bound Laboratory Notebook:  You are required to have a laboratory notebook with permanently bound pages. You must bring this laboratory notebook with you to lab in order to collect lab data. You may not refer to the printed laboratory manual (Chemical Principles in the Laboratory) during lab.  Prior to each laboratory you may transfer to your laboratory notebook all the notes and data tables that are necessary for you carry out that lab.

 

Safety Goggles and Lab Coats: You will be supplied with this required safety gear prior to the first laboratory; if these are lost or misplaced, you must purchase replacements.  You cannot participate in any laboratory activity without wearing this required safety gear.

 

 

Grading:

Quizzes: There will be a number of unannounced quizzes given during lecture periods throughout the semester. The subject of each quiz will generally be a class topic discussed since the last quiz. 

 

Mid-term Exam: There will be one mid-term exams currently scheduled for February 16 and March 22 respectively.  The first exam will be based on the material covered in Chapters 12-14 of the text.  The second exam will be based on the material covered in Chapters 15-18 of the text.

Laboratory & Assignments:  Each laboratory will require some kind of report which will be graded. In addition, you will receive a participation grade in this category from your laboratory instructors based on your willingness to seek assistance in working problems.

 

Final Examination:  Final (comprehensive) exam is currently scheduled on May 4, 2004. The exam will be based on the material covered in Chapters 11-21 of the text.

 

The final grade will reflect the following distribution of course contributions:

 

 

Points/each

Points total

% in the final grade

Mid-term exam

 

100

100

17%

Final exam

200

200

33%

Quizes

10

Normalized to 100

17%

Lab. reports

20

Normalized to 200

33%

Total (max)

 

600

100%

 

 

The final letter grades will be calculated as follows:

 

A≥90%; B+≥85%; B≥80%; C+≥75%; C≥70%; D≥60%; F<60%)

 

 

 

Course Schedule

 

Date

Day

Reading

Lecture Topic

Lab Schedule

1/12

M

10.6

Introduction. Phase equilibria.

No lab

1/13

T

 

Lab safety briefing

No lab

1/14

W

10.7

Osmosis, Cell membranes, Surfactants

No lab

1/15

R

 

No classes. Martin Luther King Jr. Birthday

No lab

 

 

 

 

 

1/19

M

12.1

Thermodynamic definitions

No lab

1/20

T

 

Check-In & Lab safety

No lab

1/21

W

12.2-12.3

Energy, Heat, Work. The 1-st Law

Chek-in, BB

1/22

R

12.4-12.5

Enthalpy, Heats of reactions

Chek-in, CC, AB

 

 

 

 

 

1/26

M

13.1-13.2

Spontaneity. Energy and disorder

Chek-in, BA

1/27

T

 

Exp. 19 safety briefing and prep

Chek-in, AA

1/28

W

13.3

Entropy and the 2-d Law

Exp. 19 – Freezing point depression, BB

1/29

R

13.4-13.6

Free energy. Bioenergetics

Exp. 19, CC, AB

 

 

 

 

 

2/2

M

Chs. 12 and 13

Review of Thermodynamics

Exp. 19, BA

2/3

T

 

Exp. 20 safety briefing and prep

Exp. 19, AA

2/4

W

14.1-14.3

Reaction rates and reaction mechanisms

Exp. 20 – Rates of chem. Reactions, BB

2/5

R

14.1-14.3

Reaction rates and reaction order

Exp. 20, CC, AB

 

 

 

 

 

2/9

M

14.4-14.6

Reaction rates and temperature

Exp. 20, BA

2/10

T

 

Exp. 22 safety briefing and prep

Exp. 20, AA

2/11

W

14.6

Activation energy.

Exp. 22 – Chem. Equilibrium, BB

2/12

R

14.7

Catalysis

Exp. 22, CC, AB

 

 

 

 

 

2/16

M

Ch. 14

Review of Kinetics

Exp. 22, BA

2/17

T

 

Exp. 23 safety briefing and prep

Exp. 22, AA

2/18

W

15.1-15.2

Chemical equilibrium. Equilibrium constant

Exp. 23 – Equilibrium constant, BB

2/19

R

15.3-15.4

Thermodynamics and equilibrium

Exp. 23, CC, AB

 

 

 

 

 

2/23

M

15.5-15.6

Working with equilibria I

Exp. 23, BA

2/24

T

 

Exp. 24 safety briefing and prep

Exp. 23, AA

2/25

W

15.5-15.6

Working with equilibria II

Exp. 24 – Molar mass determination, BB

2/26

R

16.1-16.3

Acid-base equilibria I

Exp. 24, CC, AB

 

 

 

 

 

3/1

M

16.4-16.7

Acid-base equilibria II

Exp. 24, BA

3/2

T

17.1-17.3

Buffers

Exp. 24, AA

3/3

W

17.4-17.5

Solubility equilibria. Complexes

 

3/4

R

Chs. 12-17

Mid-term Exam

 

 

Date

Day

Reading

Lecture Topic

Lab Schedule

3/8-11

M-R

 

Spring Break

 

 

 

 

 

 

3/15

M

18.1-18.4

Redox reactions and cell potentials

 

3/16

T

 

Exp. 25 safety briefing and prep

 

3/17

W

18.5-18.6

The Nernst equation.

Exp. 25 – Buffers, BB

3/18

R

18.7

Elelctrolysis

Exp. 25, CC, AB

 

 

 

 

 

3/22

M

Chs. 15-18

Review of chemical equilibria

Exp. 25, BA

3/23

T

 

Exp. 26 safety briefing and prep

Exp. 25, AA

3/24

W

19.1-19.3

Transitional metals. Complexes

Exp. 26 – Solubility, BB

3/25

R

19.4

Metallurgy

Exp. 26, CC, AB

 

 

 

 

 

3/29

M

19.5-19.6

Transitional metals. Applications

Exp. 26, BA

3/30

T

 

Exp. 28 safety briefing and prep

Exp. 26, AA

3/31

W

20.1-20.3

The main group elements. Metals

Exp. 28- Hardness of water, BB

4/1

R

20.4-20.5

The main group elements. Phosphorus

Exp. 28, CC, AB

 

 

 

 

 

4/5

M

20.6

The main group elements. Sulfur, Halogens

Exp. 28, BA

4/6

T

 

 

Exp. 28, AA

4/7

W

21.1-21.2

Nuclear chemistry and nuclear decay

No lab

4/8

R

 

Holy Thursday

No lab

 

 

 

 

 

4/12

M

 

Easter Monday

No lab

4/13

T

 

Exp. 30 safety briefing and prep

No lab

4/14

W

21.3-21.4

Nuclear fission and nuclear fusion

Exp. 30 – Redox titration, BB

4/15

R

21.5-21.7

Radioactivity

Exp. 30, CC, AB

 

 

 

 

 

4/19

M

11.1-11.4