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Department of Chemistry and Biochemistry, Seton Hall University
Alexander Y. Fadeev, Ph.D. Associate Professor Chemistry of Surfaces
and Interfaces
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McNulty Hall: 318 (office), 304 (lab) fadeeval@shu.edu
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Research in our group centers around chemistry of solid surfaces. We are interested in monomolecular layers and thin organic films supported on surfaces of inorganic solids (metals, metal oxides, phosphates and others). This chemistry enables one to control interactions at solid-solid, solid-liquid, and solid-vapor interfaces. Advanced applications of such materials are in the areas of adsorption and separation science, wettability and adhesion, biomaterials, and sensors. Some examples are demonstrated below.
1. Hydrolysis and condensation of
tetraethoxysilanes under certain conditions produce silica particles with uniform
geometry, e.g. microspheres (left) or ordered mesopores (right) .
Covalent modification of silicas with organosilanes produce solids with controlled
surface functionality
3. Water-Hydrophobic interface is of great fundamental importance (and complexity!) for understanding adsorption and wetting at nano-scale. We combine microscopic (ellipsometry) and macroscopic (adsorption, water intrusion, and contact angles) approaches in characterization of water-hydrophobic interactions in model surfaces as well as in real systems, e.g. hydrophobic stationary phases in HPLC.
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Department of Chemistry and |